Spectrophotometric determination of micro amount of molybdenum (VI)

Spectrophotometric Determination of Trace amounts of Molybdenum(VI) Using 4-Hydroxybenzaldehydethiosemicarbazone

The reagent 4-hydroxybenzaldehyde thiosemicarbazone (4-HBTS) has been used for the determination of Mo(VI) by spectrophotometric method. The reagent 4-HBTS gives green colour with Mo(VI) solution of weak acidic medium and the maximum absorbance was observed at 365nm, in acidic buffer p H 6.0. The molar absorptivity and Sandell’s sensitivity of Mo(VI)4-HBTS complex are 1.25 x 10 L mol cm and 0.0...

Simultaneolls spectrophotometric determination of molybdenum ( VI ) and titanium ( IV ) using 2 , 4 - dihydroxybenzaldehyde isonicotinoyl hydrazone

Determination of molybdenum(VI) by direct spectrophotometry and simultaneous determination of molybdenum(VI) and titanium(IV) are reported. Molybdenum(VI) gives a golden yellow colour with 2,4dihydroxybenzaldehyde isonicotinoyl hydrazone with a 1:2 metal-reagent stoichiometry at pH 1.5. The complex shows an absorption maximum at 445 nm with molar absorptivity and Sandell's sensitivity of 1.02x1...

Spectrophotometric determination of molybdenum using surfactant-mediated liquid–liquid extraction

A new spectrophotometric method has been developed for determination of molybdenum using surfactantmediated liquid–liquid extraction. Molybdenum(V) obtained by ascorbic acid reduction in 2.5 M H2SO4 reacted spontaneously with thiocyanate and cetyl trimethyl ammonium bromide (CTAB), forming an intense orange yellow complex that was extracted quantitatively into 1,2-dichloroethane and absorbed at...

Utilization of Cloud-Point Preconcentration for Spectrophotometric Determination of Trace Amounts of Molybdenum(VI) in Plants and Water Samples

A cloud-point preconcentration process using micelle of the non-ionic surfactant Triton X-114 to extract Mo(VI) from aqueous solutions was investigated. The method is based on the color reaction of molybdenum with 5-(2-benzothiazolyl-azo)8-hydroxy-quinoline (BTAHQ) in the presence of potassium bromide at pH 1.75 glycine/HCl buffer media and micelle-mediated extraction of complex. The optimal ex...

Spectrophotometric determination of molybdenum(VI) using isothipendyl hydrochloride and pipazethate hydrochloride in alloy steels and soil samples.